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 Anastopoulos - Tzamalis Anastos, Professor
Laboratory: Physical Chemistry
PHONE:+30 +302310997861
Research Areas

1. Study of the structure of the Hg, Ag, Au, Cu, Ni, Bi electrodes-aqueous, non-aqueous and mixed solution interface by differential capacitance measurements. Study of frequency dispersion effects and of the fractal morphology of adsorbed layers at electrochemical interfaces of the above electrodes by means of electrochemical impedance spectroscopy.

2. Correlation of bulk properties of solvent systems with the structure of electrochemical interfaces and the interfacial behaviour of surface active compounds.

3. Study of the mechanism of cation electroreduction at the Hg electrode.

4. Mathematical simulation of impedance characteristics of MOS, MOSE and SOE structures.


 Selected Publications
1. A.Papaderakis, A.G.Anastopoulos, S.Sotiropoulos 
"Electrochemical studies of processes occuring at the polycrystalline Cu electrode/methanol interface", Journal Electroanalytical Chemistry, 783, 217-225, (2016)
2. A.G.Anastopoulos, A.D.Papoutsis,A.A.Papaderakis 
"Differential capacitance and electrochemical impedance study of surfactant adsorption on polycrystalline Ni electrode ", Journal of Solid State Electrochemistry, 19, 2369-2377, (2015)
3. A.G.Anastopoulos and A.A.Papaderakis 
"On the origin of frequency dispersion at the interface between mercury electrode and aqueous solutions of alkali halides", Russian Journal of Electrochemistry, 50, 78-88, (2014)
4. A.G.Anastopoulos, M. Paschalidou, A. Papoutsis 
"Structural changes at the interface between polycrystalline Ag and electrolyte solutions containing surfactants as probe molecules", Journal of Electroanalytical Chemistry, 720, 52-57, (2014)
5. A.Papoutsis, A.G.Anastopoulos, A.Papaderakis, M.Paschalidou 
"Morphological changes at the Hg/solution interface related to the presence of adsorbed cations combined with solvent properties", Journal of Solid State Electrochemistry, 17, 547-553, (2013)
6. A.G.Anastopoulos and A.I.Bozatzidis 
"On the fractality of Hg/ non-aqueous solution interfaces", Russian Journal of Electrochemistry, 47(1), 53-58, (2011)
7. A.G.Anastopoulos, A.I.Bozatzidis 
"Detection of the fractal character of compact adsorbed layers by the dropping mercury electrode.", Electrochimica Acta, 54, 4099, (2009)
8. A.G.Anastopoulos 
"Kinetics of aqueous amalgam formation electrode reactions by the combined analysis of interfacial distance parameters and steric factors", Research & Reviews in Electrochemistry, Vol.1, Issue 2, (2008)
9. A.G.Anastopoulos 
"Modeling nanoscale MOS capacitors", Materials Science an Indian Journal, Vol.4, Issue 4, (2008)
10. Andreas Bozatzidis, Anastos G.Anastopoulos, Theodoros Laopoulos 
"Automated Data Acquisition Setup for Interfacial Tension and Capacitance measurements at Hg-Solution Contacts under LabVIEW Control", Electroanalysis, 19, 1711, (2007)
11. A.G.Anastopoulos and Th.Latsinoglou 
"Correlation of Kinetic and Thermodynamic Quantities of Tl(I)/Tl(Hg) Electroreduction with Parameters of Binary Mixtures of Water with Acetone, Acetonitrile, Methanol and N,N-dimethylformamide", Journal of Solution Chemistry, 34, 1341, (2005)
12. A.G.Anastopoulos, G.Nikolaidis 
"Mechanism of Amalgam Formation Electrode Reactions in Non Aqueous Solvents. Combined Analysis of Interfacial Distance parameters and Steric factors", J.Electroanal.Chem., 571, 309, (2004)
13. A,G.Anastopoulos 
"Solvent effects on the Gibbs energy of Adsorption of Neutral organic compounds. ", Z.Phys.Chemie, 216, 1095, (2002)
14. A.G.Anastopoulos 
"Combined analysis of interfacial distance parameters and steric factors for the kinetic study of retarded amalgam formation reactions under conditions of constant electrode coverage. Cd(II)/Cd(Hg) reduction in N-methyl formamide as a model reaction. ", J.Phys.Chem. B, 104, 5102, (2000)
15. A.G.Anastopoulos, P.Hadjiloizou and D.Nikoletou 
"Interfacial rearrangements at the Mercury electrode in non-aqueous solvents of high dielectric constant. Reorientation of triphenylbismouth and triphenylantimony. ", Langmuir, 16, 7789, (2000)
 Research Projects
1. Electrochemical characterization of the structure and morphology of the interface between polycrystalline metal electrodes and electrolyte solutions. Study of phase development and phase transitions.
Research Committee. Aristotle University of Thessaloniki
2013 - 2014
1. Chapters of Physical Electrochemistry
A.G.Anastopoulos, P. Nikitas, Pages:199 (2000)
2. SOLUTION CHEMISTRY RESEARCH PROGRESS: Dependence of the Gibbs Energy of Adsorption of Neutral Organophosphorous Compounds on Empirical Indices of Binary Solvent Mixtures
A.G.Anastopoulos (invited), Editor: D.Bostrelli, NOVA SCIENCE PUBLISHERS INC NEW YORK,ISBN:1-60021-993-4, Pages:115-131 (2008)
3. Physical Chemistry of Electrochemical Systems
A.G.Anastopoulos, P.Nikitas, Pages:194 (1987)
4. HANDBOOK ON THE CLASSIFICATION AND APPLICATION OF FRACTALS: Formation of fractal layers on mercury surfaces.
A.G.Anastopoulos (invited),Ed.Kyle J.Brennan,Nova Science Publishers, New York, 2011., Pages:95-113 (2011)
  School of Chemistry
Aristotle University of Thessaloniki